中国乳业 ›› 2026, Vol. 0 ›› Issue (7): 137-144.doi: 10.12377/1671-4393.26.07.18

• 质量安全 • 上一篇    下一篇

电导率仪检定方法及其在乳制品行业中的应用

张永健, 高万东, 齐静, 董隐   

  1. 内蒙古伊利实业集团股份有限公司,呼和浩特 010110
  • 发布日期:2026-08-19
  • 作者简介:张永健(1973-),男,内蒙古呼和浩特人,本科,工程师,研究方向为轻工乳品工程技术和计量应用;高万东(1972-),男,河北张家口人,本科,高级工程师,研究方向为乳制品质量和工艺管理;齐 静(1989-),女,辽宁阜新人,本科,工程师,国家二级注册计量师,研究方向为计量设备的自动化校准;董 隐(1982-),女,内蒙古呼和浩特人,本科,国家二级注册计量师,研究方向为计量设备校准。

Calibration Method for Conductivity Meters and its Application in the Dairy Industry

ZHANG Yongjian, GAO Wandong, QI Jing, DONG Yin   

  1. Inner Mongolia Yili Industrial Group Co.,Ltd.,Hohhot Inner Mongolia 010110
  • Published:2026-08-19

摘要: [目的] 针对乳制品行业生产过程对电导率仪校准的特殊需求,提出一种适用性强的新型校准方法,并系统分析电导率仪在乳制品行业中的应用现状与发展前景。[方法] 基于专用电导率仪检定装置,在5×10-2~2×105μS/cm测量范围内,对电导率仪的示值误差进行不确定度评定;按照JJG 376—2007规程要求,采用标准溶液进行电极常数标定,并结合温度补偿参数开展有补偿与无补偿两种模式下的校准测试。[结果] 该检定装置在测量范围内的相对扩展不确定度为Urel=0.32%(k=2),重复性测量引入的不确定度分量u1=0.026%,标准溶液引入的不确定度分量u3=0.125%,合成标准不确定度为0.16%。在此基础上,初步构建了适用于乳制品行业的电导率仪校准操作规范,并提出一种简便可行的校准测试方法。[结论] 该研究为乳制品生产过程中电导率仪的检定与校准工作提供了有效技术支持,同时结合原料乳检测、生产过程监控、CIP清洗控制及信息化系统集成等应用场景,系统阐明了电导率仪在保障乳品质量与工艺稳定性方面的广泛应用价值。

关键词: 电导率仪, 校准, 不确定度, 温度补偿

Abstract: [Objective] In response to the specific requirements for conductivity meter calibration in dairy production processes,this paper proposed a novel calibration method with strong applicability,and systematically analyzed the current application status and development prospects of conductivity meters in the dairy industry. [Method] Based on a dedicated verification device for conductivity meters,the uncertainty of the indicated error of the conductivity meter was evaluated within the measuring range of 5×10-2 to 2×105 μS/cm. In accordance with the requirements of the JJG 376—2007 verification regulation,standard solutions were used for electrode constant calibration,and calibration tests were carried out under both compensated and uncompensated modes in conjunction with temperature compensation parameters. [Result] The relative expanded uncertainty of the verification device within the measuring range was Urel=0.32% (k=2),with the uncertainty component introduced by repeatability measurements u1= 0.026%,the uncertainty component introduced by the standard solution u3=0.125%,and the combined standard uncertainty of 0.16%. On this basis,a set of operational specifications for calibrating conductivity meters tailored to the dairy industry was preliminarily established,and a simple and feasible calibration testing method was proposed. [Conclusion] This research provides effective technical support for the verification and calibration of conductivity meters used in dairy manufacturing processes. Furthermore,by integrating application scenarios such as raw milk inspection,production process monitoring,CIP cleaning control,and information system integration,it systematically elucidates the extensive application value of conductivity meters in ensuring dairy quality and process stability.

Key words: conductivity meter, calibration, measurement uncertainty, temperature compensation

[1] 于得水,李域,龚敏珍.在线电导率仪计量现状及校准方法研究[J].计量技术,2017(10):58-61.
[2] 董阿力德尔图,吴海霞,张艳玲.液奶生产过程质量安全控制技术[M].北京:化学工业出版社,2023:168-196.
[3] 窦少华,王伟,赵长新.电导率监测在啤酒发酵过程中的应用[J].食品与生物技术学报,2008,27(4):4.
[4] 王中州,胡建民,程桂苹.瓶装饮用纯水卫生标准制定研究[J].食品科学,1998,19(6):36-38.
[5] 赵荣梅,蔡阳,李海芳.制药用水电导率的测量不确定度评定[J].应用化工,2021,50(S2):408-410.
[6] 王玉万,郭正.电导率仪在测定发酵液体积中的应用[J].微生物学通报,1993,20(3):2.
[7] 赵立,侯小东.浅议在线电导率仪校准的重要意义[J].中国机械,2019(8):57.
[8] JJG 376—2007 中华人民共和国国家计量检定规程电导率仪[S].
[9] Pratt K W,Koch W F,Wu Y C,et al.Molality-based primary standards of electrolytic conductivity(IUPAC technical report)[J].Pure and Applied Chemistry,2001,73(11):1783-1793.
[10] 张国城. 关于电导率仪中温度补偿的讨论[J].中国计量,2010(1):114-116.
[11] JJF1059.1—2012 中华人民共和国国家计量技术规范测量不确定度评定与表示[S].
[12] Commission Regulation(EC)No1854/96 establishing a list of reference methods for analysis and quality evaluation of raw milk and dairy products[S].
[13] Commission Regulation(EC)No 273/2008 Detailed analytical test rules for raw milk and dairy products[S].
[14] 孟雪,赵海波,刘冉.乳品CIP数字化双电极在线电导率计量校准装置和校准方法的研究[J].工业计量,2023,33(1):1-3,8.
[1] 冯美红. 高效液相色谱法测定巴氏杀菌乳中乳铁蛋白含量的不确定度评定[J]. 中国乳业, 2025, 0(12): 65-70.
[2] 王晴, 孙玉荣, 李静, 张文霞, 王斌. 乳品检测仪器设备期间核查的理论与实践研究[J]. 中国乳业, 2025, 0(11): 160-166.
[3] 陈炜楠, 杨爱君, 何瑛, 梁俊健, 曹学思. 生乳中抗生素测定值的不确定度测定——基于SNAP双流向酶联免疫法[J]. 中国乳业, 2024, 0(6): 80-84.
[4] 陈炜楠, 杨爱君, 何瑛, 梁俊健, 曹学思. 胶体金免疫层析法测定生乳中抗生素含量的不确定度[J]. 中国乳业, 2024, 0(12): 104-108.
[5] 曹学思, 何瑛, 杨爱君, 纪坤发, 罗少杰, 林淑仪, 叶绮薇. 凯氏定氮法测定巴氏杀菌乳中蛋白质含量的不确定度评定[J]. 中国乳业, 2024, 0(11): 108-113.
[6] 邢益俊, 刘传栩, 杨爱君, 何瑛, 纪坤发. 火焰原子吸收光谱法测定牛乳中钙含量的不确定度评定[J]. 中国乳业, 2023, 0(12): 79-85.
[7] 李婕, 曹学思, 杨爱君, 陈欣, 陈蓓蕾. 酶联免疫法测定乳粉中黄曲霉毒素M1含量的不确定度评定[J]. 中国乳业, 2023, 0(11): 75-80.
[8] 何瑛, 曹学思, 纪坤发, 杨爱君, 陈欣, 陈春裕. 高效液相色谱法测定巴氏杀菌乳中糠氨酸含量的不确定度评定[J]. 中国乳业, 2022, 0(9): 71-80.
[9] 顾晟琳, 夏亚文, 徐琼. 乳粉中金黄色葡萄球菌测定不确定度评定[J]. 中国乳业, 2022, 0(12): 115-119.
[10] 陈春裕, 纪坤发, 何瑛, 杨爱君*. 乳粉溶解度测定的不确定度评定[J]. 中国乳业, 2022, 0(12): 110-114.
[11] 葛萃萃, 王文祥, 吴曙霞, 张惠君, 王潇, 秦芸桦, 王静. 婴儿配方奶粉中二十碳四烯酸的测量不确定度评定[J]. 中国乳业, 2022, 0(12): 104-109.
[12] 杨美丰, 纪坤发, 何瑛, 杨爱君. 分光光度法测定牛乳中亚硝酸盐含量的不确定度评定[J]. 中国乳业, 2022, 0(10): 82-89.
[13] 崔承远. 婴幼儿配方乳粉中1,3-二油酸-2-棕榈酸甘油三酯的测量不确定度评估[J]. 中国乳业, 2022, 0(1): 63-68.
[14] 陈忱. 婴幼儿配方乳粉叶黄素含量检测不确定度的评定[J]. 中国乳业, 2021, 0(8): 107-112.
[15] 吴舒敏, 林木娣. 牛乳中大肠菌群平板计数法不确定度的评定[J]. 中国乳业, 2021, 0(7): 98-101.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!